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Check the tail before you choose
Ц is ts; Ч is ch; Ш is sh; Щ is sh followed by ch. The small lower-right tail distinguishes Щ from Ш.
One letter, two cases
Ц is ts; Ч is ch; Ш is sh; Щ is sh followed by ch. The small lower-right tail distinguishes Щ from Ш. Compare the examples side by side. Letter names label the characters; the sound cues explain how to pronounce them.
tse
Ц ц makes ts, as at the end of cats. Look for two uprights and the small tail at the lower right.
ц
tse
che
Ч ч makes ch, as in chair. Its upper part is open; compare it with Ц ц and Ш ш.
ч
che
sha
Ш ш makes sh. It has three uprights joined along the bottom and no extra lower-right tail.
ш
sha
shcha
Щ щ makes sh followed by ch. It resembles Ш ш but adds a small tail at the lower right.
щ
shcha