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Ie and ei: order changes the sound
Read Liebe and Wein, then meet eu and äu.
Ie usually spells a long i
In Liebe, sieben and Biene, ie is /iː/, one long vowel like English ee. This is the common pattern, not a promise for every loanword: Familie has a different ending.
ie
long i
Ei is a diphthong
Ei in Wein and mein moves between two vowel positions: /aɪ̯/, roughly English eye. Eu and äu both give /ɔʏ̯/ in neu and Häuser.
ei
eye-like diphthong